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14452-75-6

Name CALCIUM
CAS 14452-75-6
Molecular Formula Ca
MDL Number MFCD00085314
Molecular Weight 40.08
MOL File 14452-75-6.mol

Chemical Properties

form  Liquid
color  Clear colorless
Water Solubility  Miscible with water.
Dielectric constant 3.0(Ambient)
Exposure limits ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
History Though lime was prepared by the Romans in the first century under the name calx, Calcium was not discovered until 1808. After learning that Berzelius and Pontin prepared calcium amalgam by electrolyzing lime in mercury, Davy was able to isolate the impure metal. Calcium is a metallic element, fifth in abundance in the Earth’s crust, of which it forms more than 3%. It is an essential constituent of leaves, bones, teeth, and shells. Never found in nature uncombined, it occurs abundantly as limestone (CaCO3), gypsum (CaSO4·2H2O), and fluorite (CaF2); apatite is the fluorophosphate or chlorophosphate of calcium. Calcium has a silvery color, is rather hard, and is prepared by electrolysis of the fused chloride to which calcium fluoride is added to lower the melting point. Chemically it is one of the alkaline earth elements; it readily forms a white coating of oxide in air, reacts with water, burns with a yellowred flame, largely forming the oxide. The metal is used as a reducing agent in preparing other metals such as thorium, The Elements 4-7 uranium, zirconium, etc., and is used as a deoxidizer, desulfurizer, and inclusion modifier for various ferrous and nonferrous alloys. It is also used as an alloying agent for aluminum, beryllium, copper, lead, and magnesium alloys, and serves as a “getter” for residual gases in vacuum tubes. Its natural and prepared compounds are widely used. Quicklime (CaO), made by heating limestone and changed into slaked lime by the careful addition of water, is the great cheap base of the chemical industry with countless uses. Mixed with sand it hardens as mortar and plaster by taking up carbon dioxide from the air. Calcium from limestone is an important element in Portland cement. The solubility of the carbonate in water containing carbon dioxide causes the formation of caves with stalactites and stalagmites and is responsible for hardness in water. Other important compounds are the carbide (CaC2), chloride (CaCl2), cyanamide (CaCN2), hypochlorite (Ca(OCl)2), nitrate (Ca(NO3)2), and sulfide (CaS). Calcium sulfide is phosphorescent after being exposed to light. Natural calcium contains six isotopes. Sixteen other radioactive isotopes are known. Metallic calcium (99.5%) costs about $200/kg.
Uses
Calcium is an alkaline earth element that contributes toward bone and teeth formation, muscle contraction, and blood clotting. it occurs in milk, vegetables, and egg yolk.

Safety Data

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H261
Precautionary statements  P231+P232
RIDADR  UN 1401 4.3/ PGII
RIDADR  UN 1855 4.2/ PGI
HazardClass  4.2
HazardClass  4.3
PackingGroup  I
PackingGroup  II

Hazard Information

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