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Dimethicone

Product Name:
Dimethicone
CAS No.
9006-65-9
Chemical Name:
Dimethicone
CBNumber:
CB0696472
Molecular Formula:
C6H18OSi2
Formula Weight:
162.37752
MOL File:
9006-65-9.mol
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Dimethicone Property

Density 
1 g/mL at 20 °C
vapor pressure 
5 mm Hg ( 20 °C)
refractive index 
n20/D 1.406
Flash point:
121 °C
solubility 
Practically insoluble in water, very slightly soluble or practically insoluble in anhydrous ethanol, miscible with ethyl acetate, with methyl ethyl ketone and with toluene.
form 
neat
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, reducing agents, organics, acids, alkalis. Corrodes many metals.
InChIKey
UQEAIHBTYFGYIE-UHFFFAOYSA-N
CAS DataBase Reference
9006-65-9
EPA Substance Registry System
Dimethicone (9006-65-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25-26
WGK Germany 
3
RTECS 
TQ2690000
Hazardous Substances Data
9006-65-9(Hazardous Substances Data)
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N-Bromosuccinimide Price More Price(1)

Sigma-Aldrich Gold
Product number:
D2200000
Product name :
Dimeticone
Purity:
European Pharmacopoeia (EP) Reference Standard
Packaging:
d2200000
Price:
$183
Updated:
2019/12/02
Buy:
Buy
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Dimethicone Chemical Properties,Usage,Production

Physical and chemical properties

Dimethyl silicone is also known as methyl silicone oil and polydimethylsiloxane liquid. It appears as colorless transparent viscous liquid, being tasteless, odorless and non-toxic. The molecular formula is CH3 [Si (cH3) 2] nSi (CH3) 3. The average molecular weight is 5000 ~ 100000. Based on the differences on the molecular weight, kinematic viscosity varies from 1.0 × 10-6 ~ 100000 × 10-6 square meters / second. Long-term use temperature range is -50 ~ 180 ℃. In isolated air or inert gas, it can be subject to long-term use at 200 ℃. Viscosity coefficient: 0.31 ~ 0.61. Surface tension: 1.59 ~ 2.15 × 10-4N / cm. Dielectric constant (23 ℃, 100Hz): 2.18 ~ 2.17. Volume resistivity (23 °C): 1.0 × 1014 to 1.0 × 1016Ωcm3. Dielectric loss tangent (23 ℃, 100Hz):0.00002~0.00004. Breakdown voltage strength: 13.7 ~ 17.7kV / mm. It is soluble in benzene, toluene, xylene and ethyl ether, partially soluble in ethanol, butanol and acetone, insoluble in cyclohexanol, methanol, paraffin oil and vegetable oil. It has excellent hydrophobic moisture resistance, good light transmission, and chemical stability. Widely used in insulation, heat, moisture-proof filler, defoamer, mold release agent, lubricant and surface treatment agent. It is produced by the reaction between octamethylcyclotetrasiloxane and hexamethyldisiloxane in the presence of concentrated sulfuric acid or tetramethylammonium hydroxide catalyst.

Toxicity

It has no obvious acute and chronic poisoning reaction to human beings and mammals, nor be mutagenic and carcinogenic. Oral, inhalation and skin contact have no obvious irritation or allergic reaction to the eyes, skin, and can’t be absorbed by the gastrointestinal tract and skin.

Chemical Properties

colourless to slightly yellow liquid

Chemical Properties

Dimethicones are clear, colorless liquids available in various viscosities.

Uses

A silicone oil consisting of a mixture of fully methylated linear siloxane polymers end-blocking with trimethylsiloxy units. Commonly used in skin and hair products.

Uses

dimethicone is a form of silicone used to give products lubricity, slip, and good feel. It can also serve as a formulation defoamer and help reduce the feeling of greasiness that some creams leave on the skin immediately upon application. In addition, dimethicone is reported to protect the skin against moisture loss when used in larger quantities. It improves product flow and spreadability. In combination with other ingredients, dimethicone becomes a good waterproofing material for sunscreen emulsions, and helps reduce the greasiness often seen in high-SPF preparations.

Indications

Silicone (dimethicone) ointments are excellent water-protective agents because they have an extremely low surface tension and penetrate crevices in the skin to form a plastic-like barrier. Further, they are nontoxic, inert, stable, and water repellent. As such, they are useful as barrier creams in industry or wherever constant or frequent exposure to aqueous compounds is a problem. They will not, however, protect well against solvents, oils, or dusts.

Definition

ChEBI: A polydimethylsiloxane macromolecule, composed of dimethylsiloxane repeating units.

Production Methods

Dimethicone isapoly (dimethylsiloxane) obtained by hydrolysis and polycondensation of dichlorodimethylsilane and chlorotrimethylsilane. The hydrolysis products contain active silanol groups through which condensation polymerization proceeds. By varying the proportions of chlorotrimethylsilane, which acts as a chain terminator, silicones of varying molecular weight may be prepared. Different grades of dimethicone are produced that may be distinguished by a number placed after the name indicating the nominal viscosity. For example, ABIL 20 (Evonik Goldschmidt UK Ltd) has a nominal kinematic viscosity of 18–22mm2/s (18–22cSt).

brand name

Sentry Dimethicone (Witco); Sentry Dimethicone Dispension (Witco).

Pharmaceutical Applications

Dimethicones of various viscosities are widely used in cosmetic and pharmaceutical formulations. In topical oil-in-water emulsions dimethicone is added to the oil phase as an antifoaming agent. Dimethicone is hydrophobic and is also widely used in topical barrier preparations. Therapeutically, dimethicone may be used with simethicone in oral pharmaceutical formulations used in the treatment of flatulence. Dimethicone is also used to form a waterrepellent film on glass containers.

Safety

Dimethicone is generally regarded as a relatively nontoxic and nonirritant material although it can cause temporary irritation to the eyes. In pharmaceutical formulations it may be used in oral and topical preparations. Dimethicones are also used extensively in cosmetic formulations and in certain food applications.
The WHO has set a tentative estimated acceptable daily intake of dimethicone with a relative molecular mass in the range of 200–300 at up to 1.5mg/kg body-weight. 
Injection of silicones into tissues may cause granulomatous reactions. Accidental intravascular injection has been associated with fatalities.

storage

Dimethicones should be stored in an airtight container in a cool, dry, place; they are stable to heat and are resistant to most chemical substances although they are affected by strong acids. Thin films of dimethicone may be sterilized by dry heat for at least 2 hours at 160°C. Sterilization of large quantities of dimethicone by steam autoclaving is notrecommended since excesswater diffuses intothe fluid causing it to become hazy. However, thin films may be sterilized by this method. Gamma irradiation may also be used to sterilize dimethicone. Gamma irradiation can, however, cause crosslinking with a consequent increase in the viscosity of fluids.

Regulatory Status

Accepted for use as a food additive in Europe. Included in the FDA Inactive Ingredients Database (oral capsules and tablets, topical creams,emulsions,lotions,and transdermal preparations).Included in nonparenteral medicines licensed in the UK. Included in the Canadian List of Acceptable Non-medicinal Ingredients.

Dimethicone Preparation Products And Raw materials Raw materials

Raw materials

Preparation Products

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Dimethicone Suppliers

Global(127)Suppliers
Univar Solutions(China) Co., Ltd.
Tel:
021-61932760- ;021-61932733-
Fax:
021-60932700
Email:
kevin.cheng@univarsolutions.com;ivy.zhuang@univarsolutions.com
Country:
China
ProdList:
210
Advantage:
58
J & K SCIENTIFIC LTD.
Tel:
010-82848833- ;010-82848833-
Fax:
86-10-82849933
Email:
jkinfo@jkchemical.com;market6@jkchemical.com
Country:
China
ProdList:
96815
Advantage:
76
Secco work (Beijing) chemical technology co., LTD
Tel:
010-69755668
Fax:
010-69755668
Email:
343367102@QQ.COM
Country:
China
ProdList:
3530
Advantage:
54
Shanghai Hanhong Scientific Co.,Ltd.
Tel:
021-54306202- ;021-54308259-
Fax:
+86-21-64545202
Email:
info@hanhonggroup.com;info@hanhonggroup.com
Country:
China
ProdList:
43258
Advantage:
64
Chemsky(shanghai)International Co.,Ltd.
Tel:
021-50135380
Email:
shchemsky@sina.com
Country:
China
ProdList:
32358
Advantage:
50
XiaoGan ShenYuan ChemPharm co,ltd
Tel:
0712-2580635- ;0712-2580635
Fax:
QQ: 1791901229
Email:
1791901229@qq.com;1791901229@qq.com;
Country:
China
ProdList:
9004
Advantage:
52
Chengdu XiYa Chemical Technology Co., Ltd.
Tel:
;
Fax:
0539-6365991
Email:
sale@xiyashiji.com;3007716753@qq.com
Country:
China
ProdList:
10518
Advantage:
57
Spectrum Chemical Manufacturing Corp.
Tel:
021-67601398-809
Fax:
021-57711696
Email:
marketing_china@spectrumchemical.com;
Country:
China
ProdList:
9688
Advantage:
60
Wuhan Fortuna Chemical Co., Ltd
Tel:
027-59207852-
Fax:
QQ:702039778
Email:
sales@fortunachem.com
Country:
China
ProdList:
2141
Advantage:
58

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