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SALCOMINE

Product Name:
SALCOMINE
CAS No.
14167-18-1
Chemical Name:
SALCOMINE
CBNumber:
CB4223164
Molecular Formula:
C16H14CoN2O2
Formula Weight:
325.23
MOL File:
14167-18-1.mol
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SALCOMINE Property

Melting point:
>300 °C
Water Solubility 
Insoluble in water. Soluble in benzene, chloroform, and pyridine.
Stability:
Stable. Incompatible with strong acids, strong oxidizing agents.
EPA Substance Registry System
Salcomine (14167-18-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
GG0590000
10
TSCA 
Yes
HS Code 
29349990
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N-Bromosuccinimide Price More Price(9)

Sigma-Aldrich Gold
Product number:
274712
Product name :
N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
Purity:
99%
Packaging:
1g
Price:
$49.7
Updated:
2019/12/02
Buy:
Buy
Sigma-Aldrich Gold
Product number:
274712
Product name :
N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
Purity:
99%
Packaging:
5g
Price:
$173
Updated:
2019/12/02
Buy:
Buy
TCI Chemical Gold
Product number:
S0318
Product name :
Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
Purity:
>95.0%(T)
Packaging:
25g
Price:
$89
Updated:
2019/12/02
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Buy
TCI Chemical Gold
Product number:
S0318
Product name :
Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
Purity:
>95.0%(T)
Packaging:
100g
Price:
$234
Updated:
2019/12/02
Buy:
Buy
Alfa Aesar Gold
Product number:
043174
Product name :
N,N'-Bis(salicylidene)ethylenediaminecobalt(II), 96%
Packaging:
1g
Price:
$14.4
Updated:
2019/12/02
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Buy
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SALCOMINE Chemical Properties,Usage,Production

Chemical Properties

black crystalline powder

General Description

A solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier.

Reactivity Profile

SALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides.

Purification Methods

The powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.]

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SALCOMINE Suppliers

Global(81)Suppliers
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel:
03-3668-0489
Fax:
03-3668-0520
Email:
Sales-JP@TCIchemicals.com
Country:
Japan
ProdList:
28448
Advantage:
80

14167-18-1, SALCOMINERelated Search:

Ethylenediamine Salicylaldehyde SALCOMINE SALCOMINE HYDRATE
  • N,N'-DISALICYLALETHYLENEDIAMINE COBALT(II)
  • N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)COBALT(II)
  • SALCOMINE
  • SALEN-CO
  • CO(SALEN)2
  • ((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n-cobal
  • ((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-cobal
  • (N,N'-Ethylenebis(salicylaldehyde iminato))cobalt(II)
  • (N,N'-Ethylenebis(salicylideniminato))cobalt
  • (sp-4-2)-
  • a13-30876[qr]
  • Bis(salicylaldehyde)ethylenediimine cobalt(ii)
  • bis(salicylaldehyde)ethylenediiminecobalt(ii)
  • Cobalt, ((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N',O,O')-
  • Cobalt, ((alpha,alpha'-(ethylenedinitrilo)di-o-cresolato)(2-))-
  • Cobalt, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-
  • Cobalt, N,N'-ethylenebis(salicylideneiminato)-
  • cobalt,((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n
  • cobalt,((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-[qr]
  • cobalt,[[2,2’-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-n,n’,
  • n,n’-bis(salicylidene)ethylenediaminecobalt(ii)salthyd.
  • n,n’-bis(salicylidene)ethylenediamino
  • n,n’-ethylenebis(salicylideneiminato)-cobal
  • N,N'-Ethylenebis(salicylideneiminato)cobalt
  • n,n-ethylenebis(salicylideneiminato)cobaltii[qr]
  • N,N'-Ethylenebis(salicylideniminato)cobalt(II)
  • o,o’)-(sp-4-2)-[qr]
  • o’)-o
  • Salcomin
  • Salcomine: (bis(Salicylaldehyde)ethylenediimine cobalt(II))
  • N,N'-Bis(salicylidene)ethylenediamine cobalt salt
  • Co(SALEN)2, Ethylenebis(salicylimine) cobalt(II) salt, Salcomine, N,Nμ-Disalicylidene-ethylenediamine cobalt(II) salt
  • Ethylenebis(salicylimine) cobalt(II) salt
  • N,N'-Bis(salicylidene)ethylenediaminecobalt(Ⅱ)
  • Salcomine, N,N'-Disalicylidene-ethylenediamine cobalt(II) salt
  • N,N'-Bis(salicyliden)ethylenediaminocobalt (ii)
  • Nsc32965
  • [2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II)
  • [Bis(salicylidene)ethylenediaminato]cobalt
  • [Bis(salicylidene)ethylenediamine]cobalt
  • [N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II)
  • [N,N'-Bis(salicylidene)ethylenediaminato]cobalt
  • [N,N'-Disalicylideneethylenediamine]cobalt
  • N,N'-Bis(salicylidene)ethylenediiminocobalt(II) N,N'-Disalicylalethylenediamine Cobalt(II) N,N'-Ethylenebis(salicylideneiminato)cobalt(II)
  • SalcoMine&nbsp
  • -Bis(salicylidene)ethylenediaMinocobalt(II)
  • N,N&priMe
  • The twosalicylaldehydeethylenediaMinecobalt
  • Co(salen)
  • <i>N,N'</i>-Bis(salicylidene)ethylenediaminocobalt(II)
  • 2,2'-((1Z,3Z)-2,3-Diaminobuta-1,3-diene-1,4-diyl)diphenol, cobalt salt
  • N,N&#8242
  • N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II)
  • N,N'-BIS(SALICYLIDENE)ETHYLENEDIIMINOCOBALT(II)
  • N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINOCOBALT(II)
  • -Disuccinimidyl Carbonate (Technical Grade)
  • salcomin[qr]
  • Salcomine powder