ChemicalBook > CAS DataBase List > Lithium carbonate

Lithium carbonate

Product Name:
Lithium carbonate
CAS No.
554-13-2
Chemical Name:
Lithium carbonate
CBNumber:
CB5852228
Molecular Formula:
CLi2O3
Formula Weight:
73.89
MOL File:
554-13-2.mol
More
Less

Lithium carbonate Property

Melting point:
720 °C
Boiling point:
1342 °C(lit.)
Density 
2.11 g/mL at 25 °C
Flash point:
1310°C
storage temp. 
Store at +5°C to +30°C.
solubility 
13g/l
pka
pKa 6.38 (Uncertain);10.25 (Uncertain)
form 
wire
color 
White
Specific Gravity
2.11
PH
10-11 (5g/l, H2O, 20℃)
Water Solubility 
13 g/L (20 ºC)
Merck 
14,5527
Solubility Product Constant (Ksp)
pKsp: 1.6
BRN 
3999191
InChIKey
XGZVUEUWXADBQD-UHFFFAOYSA-L
CAS DataBase Reference
554-13-2(CAS DataBase Reference)
NIST Chemistry Reference
Lithium carbonate(554-13-2)
EPA Substance Registry System
Lithium carbonate (554-13-2)
More
Less

Safety

Hazard Codes 
Xn,C,F
Risk Statements 
36/38-41-36/37/38-22-36-34-20/21/22-15-14-11
Safety Statements 
8-43-45-37/39-26-36/37-24/25-36/37/39-16-7/8-3/7/9
WGK Germany 
2
RTECS 
OJ5800000
10
TSCA 
Yes
HS Code 
28369100
Hazardous Substances Data
554-13-2(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 0.71 g/kg (Smyth)
More
Less

N-Bromosuccinimide Price More Price(35)

Sigma-Aldrich Gold
Product number:
13010
Product name :
Lithium carbonate
Purity:
purum, ≥99%
Packaging:
100g-r
Price:
$83.6
Updated:
2018/11/13
Buy:
Buy
Sigma-Aldrich Gold
Product number:
1369000
Product name :
Lithium carbonate
Purity:
United States Pharmacopeia (USP) Reference Standard
Packaging:
300mg
Price:
$366
Updated:
2020/08/18
Buy:
Buy
TCI Chemical Gold
Product number:
L0224
Product name :
Lithium Carbonate
Purity:
>98.0%(T)
Packaging:
25g
Price:
$18
Updated:
2020/06/24
Buy:
Buy
TCI Chemical Gold
Product number:
L0224
Product name :
Lithium Carbonate
Purity:
>98.0%(T)
Packaging:
500g
Price:
$62
Updated:
2020/06/24
Buy:
Buy
Alfa Aesar Gold
Product number:
010734
Product name :
Lithium carbonate, Puratronic?, 99.998% (metals basis excluding Ca), Ca LT 20ppm
Packaging:
50g
Price:
$80.6
Updated:
2020/06/24
Buy:
Buy
More
Less

Lithium carbonate Chemical Properties,Usage,Production

Description

Lithium carbonate (molecular structure is Li2CO3, English name is lithium carbonate) as a colorless monoclinic crystal or white powder. Density is 2.11. Melting point is 618 ℃. Without deliquescence, it is stable in the air. Low solubility in water, the solubility decreases with increasing temperature. Solubility in cold water is greater than hot water. It is Soluble in dilute acid, insoluble in alcohol and acetone. Carbon dioxide is introduced into the aqueous suspension of lithium carbonate, lithium carbonate is converted to lithium acid carbonate and dissolved. If the solution of lithium acid carbonate is heated and then it releases carbon dioxide and precipitates lithium carbonate. The nature of the lithium carbonate may be used to remove impurities from lithium carbonate. Since lithium ion has a strong polarizability, thus thermal stability of lithium carbonate is worse than other alkali metal carbonate, when heated to above the melting point, it will decompose to produce carbon dioxide and lithium oxide.
Lithium carbonate

Chemical Properties

Lithium carbonate is a white monoclinic crystalline solid. Typically for carbonates, lithium carbonate reacts with acids stronger than carbon dioxide or carbonic acid to yield the lithium salt of the acid and carbon dioxide. The reactions may be carried out in a solution, as an aqueous slurry, or, less effectively, with solid lithium carbonate.
Lithium carbonate exhibits a low water solubility for an alkali metal carbonate. The solubility decreases with increasing temperature. It is not hygroscopic and is generally stable when exposed to the atmosphere. In fact, it is the normal end compound encountered when many basic lithium compounds are exposed to the atmosphere. Lithium carbonate may be dissolved in water by conversion to the hydrogen carbonate. Releasing carbon dioxide by heating the solution of lithium hydrogen carbonate causes reprecipitation of the lithium carbonate.

Uses

The lithium carbonate industry is a global high monopoly industry, the current production capacity is mainly concentrated in three foreign manufacturers of SQM, FMC, Chemetall and so on.
Industrial lithium carbonate is used in the manufacture of other lithium salts, such as lithium chloride and lithium bromide and so on. It also acts as lithium oxide materials in enamel, glass, pottery and porcelain enamel, and it is also added to the electrolytic cell for electrolysis of aluminum to increase the current efficiency and reduce the internal resistance of the cell and the bath temperature. In medicine, it is mainly used for the treatment of mania, can improve their emotional disorders for schizophrenia. It has the effect of elevating peripheral leukocytes; can be used for synthetic rubber, dyes, semiconductor and military defense industry and so on; for the production of lithium tantalate, lithium niobate and other acoustic grade single crystal, optical grade monocrystalline etc; for preparation of the acoustic grade single crystal. 
Battery grade lithium carbonate is mainly used for the preparation of lithium cobalt oxide, lithium manganese oxide, ternary materials, lithium iron phosphate and other lithium ion battery cathode materials; used in a matrix modifier; as aneuroprotective effect of lithium carbonate in amyotrophic lateral sclerosis.

Toxicity

Lithium carbonate has a significant stimulating effect, firstly has damage on the gastrointestinal tract, kidney and central nervous system. Toxicity order of lithium compounds is Li <LiCl <Li2CO3, maximum allowable concentration: Lithium condensation and fragmentation aerosol were 0.05 mg/m3 and 0.5 mg/m3.
Wear rubber gloves and protective masks when working, in order to protect the respiratory organs against dust.

Preparation

Lithium carbonate is obtained as an intermediate product in recovery of lithium metal from its ore, spodumene (See Lithium). It is prepared by mixing a hot and concentrated solution of sodium carbonate with lithium chloride or sulfate solution.
Li2SO4+ Na2CO3→Li2CO3+ Na2SO4

Reactions

Lithium carbonate reacts with dilute acids, liberating carbon dioxide:
Li2CO3+ HCl →LiCl + CO2+ H2O
Thermal decompostion yields lithium oxide and carbon dioxide:
Li2CO3 → Li2O + CO2
Reaction with lime produces lithium hydroxide:
Li2CO3+ Ca(OH)2→2LiOH + CaCO3
The carbonate reacts with molten aluminum fluoride converting to lithium fluoride:
3Li2CO3+ 2AlF3 → 6LiF + 3CO2+ Al2O3
It combines with carbon dioxide in aqueous slurry forming soluble bicarbonate, which decomposes to carbonate upon heating:
Li2CO3+ CO2+ H2O →2LiHCO3
The bicarbonate can not be separated in solid form. It exists only in solution when carbonate dissolves in water saturated with CO2under pressure.

Chemical Properties

Lithium carbonate is a white hygroscopic powder.

Physical properties

White monoclinic crystals; refractive index 1.428; density 2.11 g/cm3; melts at 723°C; decomposes at 1,310°C; low solubility in water (1.54 g/100g) at 0°C; 1.32 g//100g at 20°C), solubility decrease with temperature (0.72g/100g at 100°C); insoluble in acetone and ethanol.

Uses

In the production of glazes on ceramic and electrical porcelain.

Uses

Lithium carbonate is used as a compound for producing metallic lithium. Lithium carbonate is the result of treating the mineral spodumene with sulfuric acid and then adding calcium carbonate. It is used as an antidepressant.

Preparation

Lithium carbonate is prepared by the precipitation of lithium ion by carbonate ion from an aqueous solution. Still another process, which is carried out on a smaller scale, is the reaction of a solution of lithium hydroxide with carbon dioxide gas. Lithium carbonate precipitates and is recovered from the supernatant solution.

Definition

lithium carbonate: A white solid,Li2CO3; r.d. 2.11; m.p. 723°C; decomposesabove 1310°C. It is producedcommercially by treating the ore with sulphuric acid at 250°C andleaching the product to give a solutionof lithium sulphate. The carbonateis then obtained by precipitationwith sodium carbonate solution.Lithium carbonate is used in the preventionand treatment of manicdepressivedisorders. It is also usedindustrially in ceramic glazes.

Indications

Lithium inhibits thyroidal incorporation of I- into Tg, as well as the secretion of thyroid hormones, but it does not inhibit the activity of the Na+-I- symporter or the accumulation of I- within the thyroid. Lithium offers no particular advantage over drugs of the thionamide class but may be employed for temporary control of thyrotoxicosis in patients who are allergic to both thionamides and iodide.

brand name

Eskalith (GlaxoSmithKline); Lithane (Bayer); Lithobid (JDS); Lithonate (Solvay Pharmaceuticals).

General Description

Lithiumcarbonate (Eskalith, Lithane) and lithium citrate(Cibalith-S) are the salts commercially available in theUnited States.

Reactivity Profile

A base. Decomposed by acids with the evolution of carbon dioxide. Fluorine burns fiercely on contact with Lithium carbonate.

Safety Profile

Human carcinogenic data. Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and subcutaneous routes. Human systemic effects by ingestion: toxic psychosis, tremors, changes in fluid intake, muscle weakness, increased urine volume, nausea or vomiting, allergic dermatitis. Human reproductive effects by ingestion: effects on newborn, including Apgar score changes and other neonatal measures or effects. Human teratogenic effects by ingestion: developmental abnormalities of the cardiovascular system, central nervous system, musculoskeletal and gastrointestinal systems. An experimental teratogen. Experimental reproductive effects. Experimental carcinogen producing leukemia and thyroid tumors. Human mutation data reported. Used in the treatment of manic-depressive psychoses. Incompatible with fluorine. See also LITHIUM COMPOUNDS.

Potential Exposure

Lithium carbonate is used in treatment of manic-depressive psychoses; to make ceramics and porcelain glaze; varnishes, dyes, pharmaceuticals, coating of arc-welding electrodes; battery alloys; nucleonics, luminescent paints; glass ceramics; lubricating greases; in aluminum production

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Purification Methods

Crystallise it from water. Its solubility decreases as the temperature is raised. The solubility in H2O is 1.3% at ~10o, and 0.7% at ~100o. [D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 987 1963, Caley & Elving Inorg Synth I 1 1939.]

Incompatibilities

The aqueous solution is a strong base. Reacts violently with acids, powdered calcium and fluorine.Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong acids, powdered calcium, fluorine, moisture. Corrodes aluminum, copper, zinc.

Less

Lithium carbonate Suppliers

Global(409)Suppliers
Shanghai guanghua technology co., LTD
Tel:
021-51098368-807
Fax:
021-52215553
Email:
chemol@126.com
Country:
China
ProdList:
43
Advantage:
58
Shandong Yinglang Chemical Co.,Ltd.
Tel:
18888295188;18888295177
Fax:
+86-531-88999750
Email:
764200894@qq.com
Country:
China
ProdList:
67
Advantage:
58
Shanghai Huayu Industrial Co., Ltd.
Tel:
18917588395
Email:
3346096010@qq.com
Country:
CHINA
ProdList:
20
Advantage:
58
Creasyn Finechem(Tianjin) Co., Ltd.
Tel:
022-83945878-
Fax:
022-83945176
Email:
export@creasyn.com
Country:
China
ProdList:
700
Advantage:
68
J & K SCIENTIFIC LTD.
Tel:
010-82848833- ;010-82848833-
Fax:
86-10-82849933
Email:
jkinfo@jkchemical.com;market6@jkchemical.com
Country:
China
ProdList:
96815
Advantage:
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel:
21-61259100-
Fax:
86-21-61259102
Email:
sh@meryer.com
Country:
China
ProdList:
40268
Advantage:
62
Alfa Aesar
Tel:
400-610-6006; 021-67582000
Fax:
021-67582001/03/05
Email:
saleschina@alfa-asia.com
Country:
China
ProdList:
30163
Advantage:
84
TCI (Shanghai) Development Co., Ltd.
Tel:
021-67121386 / 800-988-0390
Fax:
021-67121385
Email:
Sales-CN@TCIchemicals.com
Country:
China
ProdList:
24555
Advantage:
81
BeiJing Hwrk Chemicals Limted
Tel:
0757-86311057-
Fax:
0757-86311057
Email:
kennyrong@hwrkchemical.com
Country:
China
ProdList:
18708
Advantage:
55

554-13-2, Lithium carbonateRelated Search:

Lithium hydroxide monohydrate Tris(2,4-pentanedionato)chroMiuM(III) PHENYLSELENOL 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) BENZYL ISOCYANIDE Ethyl isocyanoacetate Cupric acetylacetonate Lithium carbonate-7Li Aluminum acetylacetonate METHYL ISOCYANOACETATE Lithium carbonate Ethylene carbonate Sodium carbonate Lithium Lithium chloride Carbonate DMC
  • Camcolit
  • Candamide
  • Carbolith
  • Carbolithium
  • Carbolitium
  • Carbonic acid lithium salt (Li2CO3)
  • Ceglution
  • CP 15467-61
  • CP-15,467-61
  • NSC-16895
  • Pfi-lithium
  • Pfl-Lithium
  • Phasal
  • Plenur
  • Priadel
  • Quilonorm
  • Quilonorm-retard
  • Quilonorm-retrard
  • Quilonum retard
  • quilonumretard
  • teralithe
  • LITHIUM METAL (SMALL BLOCKS / DISPERSED)
  • LITHIUM CARBONATE ACS REAGENT
  • Lithium carbonate, TraceSelect
  • Hematoxylin solution B
  • LITHIUM CARBONATE PURE
  • LITHIUM CARBONATE 99+% A.C.S. REAGENT
  • HEMATOXYLIN SOLUTION B ACC . TO WEIGERT, FOR MICROSCOPY*
  • LITHIUM CARBONATE XTRA PURE DAB PH. E&
  • LITHIUM CARBONATE R. G., REAG. ACS, REAG . PH. EUR.
  • LITHIUM CARBONATE PH EUR
  • LITHIUM CARBONATE, 99.997%
  • LITHIUM CARBONATE, ACS, FOR MICROSCOPY
  • LITHIUM CARBONATE, -40 MESH, 99%
  • LITHIUM CARBONATE, REAGENTPLUS, 99.99%
  • LITHIUM CARBONATE SIGMAULTRA
  • LithiumCarbonateGr
  • LithiumCarbonate,>99%
  • LithiumCarbonateExtraPure
  • Lithiumcarbonate,ACS,99.0%min
  • Lithiumcarbonate,98+%
  • Lithium carbonate, extra pure, 99.999%
  • Lithium carbonate, for analysis ACS, 99+%
  • LITHIUM CARBONATE 99.999%
  • LITHIUM CARBONATE REAGENT (ACS)
  • LITHIUM CARBONATE, 99.99%
  • LITHIUM CARBONATE, HIGH PURITY OPTICAL GRADE
  • LITHIUM CARBONATE, SOLUTION STRAY LIGHT FILTER
  • Lithium carbonate,99.999%,puratronic powder
  • Lithiumcarbonate(99.999%-Li)PURATREM
  • lithium carbonate, acs
  • lithium carbonate, puratronic
  • LITHIUMCARBONATE,POWDER,PRACTICAL
  • LITHIUMCARBONATE,POWDER,REAGENT,ACS
  • CARBONICACID,LITHIUM(I)SALT
  • Candrmide
  • Lithium carbonate, reagent grade, ACS
  • Lithium carbonate/ 99.995+%
Description Chemical Properties Uses Toxicity Preparation Reactions