ChemicalBook > CAS DataBase List > 1,4-Naphthoquinone

1,4-Naphthoquinone

Product Name:
1,4-Naphthoquinone
CAS No.
130-15-4
Chemical Name:
1,4-Naphthoquinone
CBNumber:
CB7381254
Molecular Formula:
C10H6O2
Formula Weight:
158.15
MOL File:
130-15-4.mol
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1,4-Naphthoquinone Property

Melting point:
119-122 °C(lit.)
Boiling point:
243.22°C (rough estimate)
Density 
1,42 g/cm3
vapor pressure 
<1 hPa (50 °C)
refractive index 
1.5300 (estimate)
Flash point:
141 °C
storage temp. 
Store below +30°C.
solubility 
0.09g/l
form 
Powder
color 
Khaki
PH
6.1 (10g/l, H2O, 20℃)
Water Solubility 
insoluble
Merck 
14,6395
BRN 
878524
Stability:
Stable. Incompatible with strong reducing agents, strong oxidizing agents.
InChIKey
FRASJONUBLZVQX-UHFFFAOYSA-N
CAS DataBase Reference
130-15-4(CAS DataBase Reference)
NIST Chemistry Reference
1,4-Naphthalenedione(130-15-4)
EPA Substance Registry System
1,4-Naphthoquinone (130-15-4)
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Safety

Hazard Codes 
T+,N,T,C,F
Risk Statements 
25-26-36/37/38-43-50-34-11
Safety Statements 
26-36/37-45-61-38-36/37/39-28A-24-16
RIDADR 
UN 2811 6.1/PG 1
WGK Germany 
3
RTECS 
QL7175000
8
Hazard Note 
Very Toxic
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
I
HS Code 
29146910
Hazardous Substances Data
130-15-4(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 190 mg/kg LD50 dermal Rat 202 mg/kg
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N-Bromosuccinimide Price More Price(20)

Sigma-Aldrich Gold
Product number:
8.06215
Product name :
1,4-Naphthoquinone
Purity:
for synthesis
Packaging:
5 g
Price:
$28.21
Updated:
2021/03/22
Buy:
Buy
Sigma-Aldrich Gold
Product number:
152757
Product name :
1,4-Naphthoquinone
Purity:
97%
Packaging:
5g
Price:
$33.3
Updated:
2020/08/18
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Buy
Sigma-Aldrich Gold
Product number:
152757
Product name :
1,4-Naphthoquinone
Purity:
97%
Packaging:
100g
Price:
$39.2
Updated:
2020/08/18
Buy:
Buy
Sigma-Aldrich Gold
Product number:
8.06215
Product name :
1,4-Naphthoquinone
Purity:
for synthesis
Packaging:
250 g
Price:
$57.35
Updated:
2021/03/22
Buy:
Buy
Sigma-Aldrich Gold
Product number:
8.06215
Product name :
1,4-Naphthoquinone
Purity:
for synthesis
Packaging:
1 kg
Price:
$182.22
Updated:
2021/03/22
Buy:
Buy
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1,4-Naphthoquinone Chemical Properties,Usage,Production

Chemical Properties

yellow to green powder

Chemical Properties

1,4-Naphthoquinone is a yellow to greenishyellow crystalline solid. Pungent odor like benzoquinone.

Uses

antibacterial, antineoplastic

Synthesis Reference(s)

Synthesis, p. 330, 1977 DOI: 10.1055/s-1977-24385
Tetrahedron Letters, 31, p. 4871, 1990 DOI: 10.1016/S0040-4039(00)97755-4

General Description

Yellow needles or brownish green powder with an odor of benzoquinone.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

1,4-Naphthoquinone may react with many acids and bases liberating heat and flammable gases (e.g., H2). The heat may be sufficient to start a fire in the unreacted portion of the ketone. May react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. May react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.

Hazard

Irritant

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition 1,4-Naphthoquinone emits toxic fumes and smoke.

Fire Hazard

Flash point data for 1,4-Naphthoquinone are not available; however, 1,4-Naphthoquinone is probably combustible.

Safety Profile

Poison by ingestion, intravenous, subcutaneous, and intraperitoneal routes. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes.

Potential Exposure

1,4-Naphthoquinone is used as a polymerization regulator for rubber and polyester resins; in the synthesis of dyes and pharmaceuticals; and as a fungicide and algicide.

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Purification Methods

Crystallise the quinone from diethyl ether (charcoal). It distils in steam. It also crystallises from *benzene or aqueous EtOH and sublimes in a vacuum. [Beilstein 7 IV 2422.]

Incompatibilities

Ketones are incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, nitrated amines, azo, diazo, azido compounds, carbamates, organic cyanates. May react with many acids and bases liberating heat and flammable gases (e.g., hydrogen) generating heat may be sufficient to start a fire in the unreacted portion of the ketone. May react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (e.g., hydrogen) and heat. Incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. May react violently with aldehydes.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

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1,4-Naphthoquinone Suppliers

Global(322)Suppliers
GuangTuo Chemical (Shanghai) Co., Ltd.
Tel:
021-60899189-8001 18918189673
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021-60899304
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gtchem@126.com
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China
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2673
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Tianjin Zhongxin Chemtech Co., Ltd.
Tel:
022-66880623;022-89880623
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86(0)22-66880086
Email:
sales@tjzxchem.com;sales@tjzxchem.com
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China
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617
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JinJin Le Chemical Co., Ltd
Tel:
10106090
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jinjinlechem@163.com
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China
ProdList:
8005
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58
Wuhan jiangxinyu Biotechnology Co., Ltd
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156-23458667-
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02787878152
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780712216@qq.com
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665
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J & K SCIENTIFIC LTD.
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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3B Pharmachem (Wuhan) International Co.,Ltd.
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Alfa Aesar
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021-67582001/03/05
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