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Ammonium acetate

Product Name:
Ammonium acetate
CAS No.
631-61-8
Chemical Name:
Ammonium acetate
CBNumber:
CB8438173
Molecular Formula:
C2H7NO2
Formula Weight:
77.08
MOL File:
631-61-8.mol
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Ammonium acetate Property

Melting point:
110-112 °C (dec.)(lit.)
Boiling point:
138.46°C (rough estimate)
Density 
1.07 g/mL at 20 °C
refractive index 
1.4350 (estimate)
Flash point:
136 °C
storage temp. 
2-8°C
solubility 
H2O: 1 M at 20 °C, clear, colorless
pka
4.6(Acetic Acid), 9.3(Ammonium Hydroxide)(at 25℃)
form 
Solid
color 
White
Odor
Slight acetic acid odor
PH
6.7-7.3 (50g/l, H2O, 25℃)
PH Range
6.7 - 7.3
Water Solubility 
1480 g/L (20 ºC)
λmax
λ: 260 nm Amax: 0.015
λ: 280 nm Amax: 0.01
Sensitive 
Hygroscopic
Merck 
14,495
BRN 
4186741
InChIKey
USFZMSVCRYTOJT-UHFFFAOYSA-N
CAS DataBase Reference
631-61-8(CAS DataBase Reference)
NIST Chemistry Reference
Ammonium acetate, anhydrous(631-61-8)
EPA Substance Registry System
Ammonium acetate (631-61-8)
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Safety

Safety Statements 
24/25
RIDADR 
UN 9079
WGK Germany 
3
RTECS 
AF3675000
3
TSCA 
Yes
HS Code 
29152900
Hazardous Substances Data
631-61-8(Hazardous Substances Data)
Toxicity
LD i.v. in mice: 1.8 mg (NH4+)/20g (Welch)
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N-Bromosuccinimide Price More Price(61)

Sigma-Aldrich Gold
Product number:
09689
Product name :
Ammonium acetate
Purity:
BioUltra, for molecular biology, ≥99.0%
Packaging:
1kg
Price:
$111
Updated:
2020/08/18
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Sigma-Aldrich Gold
Product number:
09689
Product name :
Ammonium acetate
Purity:
BioUltra, for molecular biology, ≥99.0%
Packaging:
100g
Price:
$358
Updated:
2020/08/18
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TCI Chemical Gold
Product number:
A2269
Product name :
Ammonium Acetate
Purity:
>97.0%(T)
Packaging:
250g
Price:
$18
Updated:
2020/06/24
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Alfa Aesar Gold
Product number:
011599
Product name :
Ammonium acetate, ACS, 97.0% min
Packaging:
500g
Price:
$52.6
Updated:
2020/06/24
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Buy
Alfa Aesar Gold
Product number:
011599
Product name :
Ammonium acetate, ACS, 97.0% min
Packaging:
2kg
Price:
$138
Updated:
2020/06/24
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Ammonium acetate Chemical Properties,Usage,Production

Chemical Properties

Ammonium acetate is a white, deliquescent crystalline solid with a slightly acetic odor. It is used as a reagent in analytical chemistry for determining lead and iron content,a chemical intermediate in manufacturing acetamide. It is also a diuretic in veterinary medicine, in other drugs, in textile dyeing, in meat preservative, in foam rubbers, in vinyl plastics, in stripping explosives, and in determining lead and iron content.
Ammonium acetate

Physical properties

White crystalline solid; deliquescent; melts at 114°C; decomposes at elevated temperatures; density 1.17 g/cm3 at 20°C, density of a 10% solution 1.022 g/mL, and a 50% solution 1.092 g/mL; very soluble in cold water (1,480 g/L at 4°C); also soluble in cold alcohol and acetone (78.9 g/L in methanol at 15°C); solution loses ammonia on standing and becomes acidic.

Uses

Ammonium acetate is used in the manufacture of acetamide and as a diuretic and diaphoretic in medical applications. The wool industry also uses this salt as a dye mordant.
Buffer solution; determination of lead and iron; separating lead sulfate from other sulfates.

Preparation

Ammonium acetate is manufactured by neutralizing acetic acid with ammonium carbonate or by passing ammonia gas into glacial acetic acid. Acidic ammonium acetate, CH3CO2NH4.CH3CO2H[25007-86-7], is manufactured by dissolving the neutral salt in acetic acid.

General Description

A white crystalline solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Ammonium acetate is used in chemical analysis, in pharmaceuticals, in preserving foods, and for other uses.

Air & Water Reactions

Water soluble.

Reactivity Profile

Ammonium acetate causes the decomposition of sodium hypochlorite within a few seconds [Mellor 2 Supp. 1:550 1956].

Health Hazard

Inhalation of dust irritates nose and mouth. Ingestion irritates mouth and stomach. Contact with dust causes irritation of eyes and mild irritation of skin.

Fire Hazard

Special Hazards of Combustion Products: Irritating vapors of ammonia acetic acid, and nitrogen oxides may form in fires.

Safety Profile

Poison by intravenous route. Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic fumes of NO, and NH3

Potential Exposure

Ammonium acetate is used as a chemical reagent, to make drugs; foam rubber; vinyl plastics; explosives, and to preserve foods. An environmental threat.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Crystallise it twice from anhydrous acetic acid, and dry under vacuum for 24hours at 100o [Proll & Sutcliff Trans Faraday Soc 57 1078 1961].

Incompatibilities

Combustible solid. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, sodium hypochlorite, potassium chlorate, sodium nitrite.

Ammonium acetate Preparation Products And Raw materials Raw materials

Raw materials

Preparation Products

ETHYL 2-CYANO-3-METHYL-2-PENTENOATE 5-(4-Phenyl-phenyl)thieno[2,3-d]pyrimidin-4(3H)-one ,97% 5-METHYLTHIOPHEN-2-YLMETHYLAMINE METHYL 2-AMINO-4-PHENYLTHIOPHENE-3-CARBOXYLATE 2-AMINO-4-PHENYL-THIOPHENE-3-CARBOXYLIC ACID ETHYL ESTER 2-AMINO-4-(2,4-DIMETHYL-PHENYL)-THIOPHENE-3-CARBOXYLIC ACID ETHYL ESTER THIENO[3,2-D]PYRIMIDIN-4(3H)-ONE 5-(2,4-DIMETHYL-PHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE 2-CHLORO-4-METHYLQUINOLINE-3-CARBONITRILE ORNOPROSTIL Ethyl 3-amino-4,4,4-trifluorocrotonate 5-P-TOLYL-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE Murexide ETHYL 2-AMINO-4-(4-FLUOROPHENYL)THIOPHENE-3-CARBOXYLATE 6-Fluorotryptamine hydrochloride 3-HYDROXY-4-METHOXYPHENETHYLAMINE HYDROCHLORIDE ETHYL 2-AMINO-4-[1,1'-BIPHENYL]-4-YL-3-THIOPHENECARBOXYLATE QUINOLINIMIDE 5-(4-METHOXY-PHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE 3-AMINO-3-(2-THIENYL)PROPANOIC ACID 1-(4-FLUOROPHENYL)ETHYLAMINE 5-(4-FLUOROPHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE 2,5-BIS(4-PYRIDYL)-1,3,4-THIADIAZOLE water proofing agent YS ETHYL 2-AMINO-4-(4-METHYLPHENYL)-3-THIOPHENECARBOXYLATE ETHYL 2-AMINO-4-(4-METHOXYPHENYL)-3-THIOPHENECARBOXYLATE 4'-CHLORO-2,2':6',2''-TERPYRIDINE 3,4-Diaminopyridine Montelukast 5-(4-BROMO-PHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE 1-(TERT-BUTYL)-3,5-DIMETHYL-1H-PYRAZOLE ETHYL 2-AMINO-4-(4-BROMOPHENYL)-3-THIOPHENECARBOXYLATE 2-(3H-Imidazol-4-yl)-ethylamine 4-AMINO-CHROMEN-2-ONE 4-ETHYL-6-HYDROXY-2-METHYLPYRIMIDINE 2-((E)-2-Hydroxy-3-phenylacryloyl)benzoic acid ,97% Isoquinoline, 7-(bromomethyl)- (9CI) 1-(TERT-BUTYL)-3,5-DIMETHYL-1H-PYRAZOLE-4-CARBALDEHYDE 5-PHENYL-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE (E)-3-Benzylidene-3H-isochromene-1,4-dione ,97%
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Ammonium acetate Suppliers

Global(402)Suppliers
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