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o-Anisaldehyde

Product Name:
o-Anisaldehyde
CAS No.
135-02-4
Chemical Name:
o-Anisaldehyde
CBNumber:
CB9238718
Molecular Formula:
C8H8O2
Formula Weight:
136.15
MOL File:
135-02-4.mol
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o-Anisaldehyde Property

Melting point:
34-40 °C(lit.)
Boiling point:
238 °C(lit.)
Density 
1.127 g/mL at 25 °C(lit.)
FEMA 
4077 | O-ANISALDEHYDE
refractive index 
1.5608
Flash point:
244 °F
storage temp. 
Store below +30°C.
solubility 
Solubility Slightly soluble in water; soluble in ethanol
form 
Low Melting Crystalline Mass
Specific Gravity
1.127
color 
Light yellow to pale brown
PH Range
Non1 uorescence (3.1) to green 1 uorescence (4.4)
Water Solubility 
insoluble
Sensitive 
Air Sensitive
JECFA Number
2062
BRN 
606301
Major Application
Battery, hair dyes, bird repellents, cosmetics, antibacterial, antipyretic
CAS DataBase Reference
135-02-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzaldehyde, 2-methoxy-(135-02-4)
EPA Substance Registry System
Benzaldehyde, 2-methoxy- (135-02-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-36/38
Safety Statements 
26-36-37/39
WGK Germany 
2
RTECS 
BZ2610000
9-23
TSCA 
Yes
HS Code 
29124900
Toxicity
LD50 orally in Rabbit: 2500 mg/kg LD50 dermal Rabbit > 5000 mg/kg
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N-Bromosuccinimide Price More Price(14)

Sigma-Aldrich Gold
Product number:
109622
Product name :
2-Methoxybenzaldehyde
Purity:
98%
Packaging:
2g
Price:
$18.5
Updated:
2019/12/02
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Sigma-Aldrich Gold
Product number:
1036948
Product name :
2-Methoxybenzaldehyde
Purity:
United States Pharmacopeia (USP) Reference Standard
Packaging:
3x0.5ml
Price:
$330.75
Updated:
2019/12/02
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TCI Chemical Gold
Product number:
A0479
Product name :
o-Anisaldehyde
Purity:
>98.0%(GC)
Packaging:
25g
Price:
$20
Updated:
2020/06/24
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TCI Chemical Gold
Product number:
A0479
Product name :
o-Anisaldehyde
Purity:
>98.0%(GC)
Packaging:
100g
Price:
$39
Updated:
2020/06/24
Buy:
Buy
Alfa Aesar Gold
Product number:
A10770
Product name :
2-Methoxybenzaldehyde, 98%
Packaging:
100g
Price:
$41.5
Updated:
2020/06/24
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o-Anisaldehyde Chemical Properties,Usage,Production

Description

O-Anisaldehyde (also 2-methoxybenzaldehyde) is found in cassia oil, cinnamon bark, and cinnamon bark oil. It is a clear colorless liquid with a strong aroma.
O-Anisaldehyde is used as a flavor agent in foods including nonalcoholic/alcoholic beverages, baked goods, chewing gum, confections, frozen dairy, fruit ices, hard/soft candy, instant coffee, tea, Jams, jellies, and milk products. O-Anisaldehyde has been used to examine the acaricidal activity of Periploca sepium oil and its active component against Tyrophagus and to obtain good enantioselectivities using Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding in asymmetric Henry reaction.

References

[1] George A. Burdock (2016) Fenraoli’s Handbook of Flavor Ingredients, Sixth Edition.
[2] https://www.alfa.com/en/catalog/A10770/

Description

o-Methoxybenzaldehyde has a faint, sweet, floral odor. It blends well with cassia. It has a spice-like flavor, quite bitter above 30 - 40 ppm. May be prepared from salicylaldehyde and dimethyl sulfate in weak alkaline solution.

Chemical Properties

Colorless to cream amber crystalline powder; sweet powdery hawthorn guaiacol vanilla acetophenone almond aroma.

Chemical Properties

light yellow to pale brown

Occurrence

Reported found in Cassia oil, cinnamon bark, and Cinnamon bark oil (Cinnamomum zeylanicum Blume), Sri Lanka (0.09–0.15%)

Uses

Intermediate.

Aroma threshold values

Medium strength odor; anisic type; recommend smelling in a 10.00% solution or less.

Taste threshold values

Sweet powdery guaiacol musty vanilla floral almond taste at 50 ppm in water.

Safety Profile

Moderately toxic by ingestion. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

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o-Anisaldehyde Suppliers

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135-02-4, o-AnisaldehydeRelated Search:

2,3-Dimethoxybenzaldehyde 2,4-Dimethoxybenzaldehyde 2,5-Dimethoxybenzaldehyde 2-Carboxybenzaldehyde 2-Formylbenzenesulfonic acid sodium salt 3,5-Dimethoxybenzaldehyde Anisole (Trifluoromethoxy)benzene p-Anisaldehyde 3-ANISALDEHYDE 4-Dimethylaminobenzaldehyde 4-Methoxyphenol 2,6-Dimethoxybenzaldehyde p-Hydroxybenzaldehyde Benzaldehyde 2-Nitrobenzaldehyde Guaiacol Cuminaldehyde
  • o-Anisaldehyde:2-Methoxybenzaldehyde
  • o-Anisaldehyde, 98% 100GR
  • o-Anisaldehyde, 98% 5GR
  • 2-Methoxybenzaldehyde Salicylaldehyde Methyl Ether
  • Adjacent Methoxy benzene forMaldehyde
  • o-Anisaldehyde 〔o-Methoxybenzaldehyde〕
  • 2-methoxy-benzaldehyd
  • 2-Methoxybenzenecarboxaldehyde
  • 6-Methoxybenzaldehyde
  • Benzaldehyde, o-methoxy-
  • O-METHOXYBENZALDEHYDE, NATURAL
  • o-Anisaldehyde, Salicylaldehyde methyl ether
  • 2-Methoxybenzaldehyde, o-Anisaldehyde, Salicylaldehyde methyl ether
  • o-Anisaldehyde,98%
  • 2-methoxybenzalde
  • 2-methoxyphenylformaldehyde
  • Nc 064
  • Nsc 58960
  • O-formylanisole
  • ANS, o-Anisaldehyde
  • 2-MethoxybenzaL
  • Benzaldehyde,2-methoxy-
  • SALICYLALDEHYDE METHYL ETHER
  • O-ANISALDEHYDE
  • O-METHOXYBENZALDEHYDE
  • ANISALDEHYDE,2-
  • 2-METHOXYBENZALDEHYDE
  • 2-ANISALDEHYDE
  • AKOS BBS-00003204
  • 2-Methoxybenzaldehyde/o-Anisadehyde
  • MethoxybenzaldehydeAnisaldehyd
  • ortho-anisaldehyde
  • 2-Methoxybenzaldehyde (o-Anisaldehyde)
  • METHYLSALICYLALDEHYD
  • 2-METHOXYBENZALDEHYDE (O-METHOXYBENZALDEHYDE)
  • ANISALDEHYDE,2-(RG)
  • O-ANISALDEHYDE 97+%
  • 2-Methoxybenzaldehyde, 98% (2-Anisaldehyd)
  • 135-02-4
  • 0135-02-04
  • CHOC6H4SO3Na
  • H3COC6H4CHO
  • ALDEHYDE
  • Building Blocks
  • Aldehydes
  • C8
  • Carbonyl Compounds
  • Organic Building Blocks
  • aldehyde
  • Fluorescent
  • Pyridines
  • Aromatic Aldehydes & Derivatives (substituted)
  • Benzaldehyde
Description References