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Methyl chloroacetate

Product Name:
Methyl chloroacetate
CAS No.
96-34-4
Chemical Name:
Methyl chloroacetate
CBNumber:
CB9854725
Molecular Formula:
C3H5ClO2
Formula Weight:
108.52
MOL File:
96-34-4.mol
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Methyl chloroacetate Property

Melting point:
-33 °C
Boiling point:
130 °C740 mm Hg(lit.)
Density 
1.238 g/mL at 25 °C(lit.)
vapor density 
3.8 (vs air)
vapor pressure 
10 mm Hg ( 25 °C)
refractive index 
n20/D 1.422(lit.)
Flash point:
125 °F
storage temp. 
Flammables area
solubility 
51.6g/l (slow decomposition)
form 
Liquid
color 
Clear colorless
PH
4.6 (28g/l, H2O, 20℃)
explosive limit
4.6-18.5%(V)
Water Solubility 
28 g/L (20 ºC)
Merck 
14,6042
BRN 
506255
CAS DataBase Reference
96-34-4(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, chloro-, methyl ester(96-34-4)
EPA Substance Registry System
Acetic acid, 2-chloro-, methyl ester (96-34-4)
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Safety

Hazard Codes 
T,Xi,F
Risk Statements 
10-23/25-37/38-41-40-36/37/38-38
Safety Statements 
26-37/39-45-36-16
RIDADR 
UN 2295 6.1/PG 1
WGK Germany 
2
RTECS 
AF9500000
19
Autoignition Temperature
869 °F
TSCA 
Yes
HS Code 
2915 40 00
HazardClass 
6.1
PackingGroup 
I
Hazardous Substances Data
96-34-4(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 107 mg/kg
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N-Bromosuccinimide Price More Price(8)

Sigma-Aldrich Gold
Product number:
108413
Product name :
Methyl chloroacetate
Purity:
99%
Packaging:
500g
Price:
$34.6
Updated:
2019/12/02
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Sigma-Aldrich Gold
Product number:
108413
Product name :
Methyl chloroacetate
Purity:
99%
Packaging:
1kg
Price:
$52.2
Updated:
2019/12/02
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Alfa Aesar Gold
Product number:
A10325
Product name :
Methyl chloroacetate, 99+%
Packaging:
2500g
Price:
$95.1
Updated:
2019/12/02
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Alfa Aesar Gold
Product number:
A10325
Product name :
Methyl chloroacetate, 99+%
Packaging:
250g
Price:
$17.7
Updated:
2019/12/02
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Sigma-Aldrich Gold
Product number:
8.02413
Product name :
Methyl chloroacetate for synthesis. CAS 96-34-4, EC Number 202-501-1, chemical formula ClCH COOCH ., for synthesis
Packaging:
8024130100
Price:
$28.8
Updated:
2019/12/02
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Methyl chloroacetate Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

As solvent.

General Description

A crystalline solid or a solid dissolved in a liquid. Insoluble in water and denser than water. Contact may slightly irritate skin, eyes and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Methyl chloroacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Toxic by ingestion and inhalation.

Health Hazard

Extremely corrosive to the eyes, skin, nose, throat, and upper respiratory tract. Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

Fire Hazard

Special Hazards of Combustion Products: Toxic fumes of hydrogen chloride

Safety Profile

Poison by ingestion. Moderately toxic by inhalation and subcutaneous routes. Flammable when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl-.

Purification Methods

Shake the ester with saturated aqueous Na2CO3 (three times), aqueous 50% CaCl2 (three times), saturated aqueous NaCl (twice), dry (Na2SO4) and fractionally distil it. Very toxic. [Beilstein 2 IV 480.]

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Methyl chloroacetate Suppliers

Global(269)Suppliers
IGM RESINS
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