Diallyl phthalate Chemical Properties
- Melting point:
- -70 °C
- Boiling point:
- 165-167 °C5 mm Hg(lit.)
- 1.121 g/mL at 25 °C(lit.)
- vapor density
- 8.3 (vs air)
- vapor pressure
- 2.3 mm Hg ( 150 °C)
- refractive index
- Flash point:
- >230 °F
- storage temp.
- Clear colorless to light yellow
- Water Solubility
- 6 g/L (20 ºC)
- CAS DataBase Reference
- 131-17-9(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,2-Benzenedicarboxylic acid, di-2-propenyl ester(131-17-9)
- EPA Substance Registry System
- Diallyl phthalate (131-17-9)
Diallyl phthalate Usage And Synthesis
clear colourless to light yellow liquid
Diallyl Phthalate is used as a reagent in ring-closing ruthenium based reactions.
Clear pale-yellow liquid. Odorless.
Air & Water Reactions
Incompatible with water and oxygen. Should be stored air tight, with inhibitor, to prevent polymerization reaction .
Diallyl phthalate can react with oxidizers. Diallyl phthalate can also react with acids and alkalis. Diallyl phthalate is incompatible with water and oxygen.
Diallyl phthalate is combustible.
Suspected carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, intraperitoneal, and subcutaneous routes. An eye irritant. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use CO2 or dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.
In the 103-week study referred
to previously, a slight increase in MNCL was seen in
female rats treated with 50 or 100 mg/kg/day of DAP. MNCL
occurs in F344 control rats at a high incidence; however, the
incidence of 51% in female rats at the high dose level was
above historical control data for the laboratory (29%). No
significant increases in tumor incidences were seen in male
rats. Based on this study, DAP was considered to have
demonstrated equivocal evidence for carcinogenicity in
female F344 rats according to the NTP.
In male and female B6C3F1 mice receiving 300 mg/kg of DAP by gavage for 103 weeks (5 days/week), the incidence of forestomach papillomas was significantly greater than that of controls. Because of the rarity of forestomach papillomas in control B6C3F1 mice and the concomitant observation of dose-related forestomach hyperplasia, the development of these tumors was considered to be test substance related. Compared to controls, a slight increase in the incidence of lymphomas was observed in males receiving 300 mg/kg/day of DAP. Because the increase was not statistically significant compared to historical control data, this effect was not considered to be test substance related.
- 2-HYDROXYMETHYL-BENZOIC ACID METHYL ESTER
- Methyl o-toluate
- ALLYL BENZYL ETHER
- ETHYL PHTHALATE MONO
- Diallyl phthalate
- Allyl chloroformate
- Potassium hydrogen phthalate
- Allyl phenoxyacetate
- Dimethyl succinate
- 1,2-Benzenedicarboxylic acid di-C9-11-branched alkyl esters C10-rich
- Bis(2-methoxyethyl) phthalate
- DIALLYL ISOPHTHALATE
- Phthalic acid
- Dibutyl phthalate
- Methyl acrylate
- Dimethyl phthalate
- Bis(2-ethylhexyl) phthalate
- BUTYL OLEATE
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