CIS-1,4-CYCLOHEXANEDIOL

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CIS-1,4-CYCLOHEXANEDIOL Basic information

Product Name:
CIS-1,4-CYCLOHEXANEDIOL
CAS:
931-71-5
MF:
C6H12O2
MW:
116.16
EINECS:
213-240-8
Mol File:
931-71-5.mol
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CIS-1,4-CYCLOHEXANEDIOL Chemical Properties

Melting point:
98-100 ºC
Boiling point:
150 ºC
Density 
1.156±0.06 g/cm3(Predicted)
Flash point:
65 ºC
pka
14.75±0.40(Predicted)
CAS DataBase Reference
931-71-5
EPA Substance Registry System
1,4-Cyclohexanediol, cis- (931-71-5)
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CIS-1,4-CYCLOHEXANEDIOL Usage And Synthesis

Uses

cis-1,4-Cyclohexanediol is an metabolite of side-chain of candesartan cilexetil (C175580), on digoxin-induced arrhythmias in dogs with congestive heart failure.

Purification Methods

Crystallise the cis-diol from acetone (charcoal), then dry and sublime it under vacuum. It also crystallises from Me2CO or Me2CO/*C6H6. The diacetate has m 40.6-41.1o (from pet ether or 34-36o from EtOH). [Grob & Baumann Helv Chim Acta 38 604 1955, Owen & Robins J Chem Soc 320 1949, Beilstein 6 III 4080, 6 IV 5209.]

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