(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties

Melting point:

330-332 °C(lit.)

alpha 

D23 +580° (c = 0.01 in ethanol)

form 

Liquid May Develop Some Turbidity or Precipitate

color 

Light yellow to gold to brown

λmax

509nm(CH2Cl2)(lit.)

Merck 

14,5252

InChIKey

LJVAWOSDJSQANR-OHRASPNLSA-K

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-20/21/22

Safety Statements 

26-36-36/37/39

WGK Germany 

3

F 

9

HS Code 

29349990

MSDS

• Language:EnglishProvider:SigmaAldrich
• Language:EnglishProvider:ACROS

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Usage And Synthesis

Chemical Properties

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is Dark brown powder or chunks

Uses

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is a coordinated compound of manganese and a salen-type ligand. It is also used as an asymmetric catalyst used to enantioselectively transform prochiral alkenes into epoxides.

Uses

Chiral catalyst for epoxidation of olefins.

Reactions

1. Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
3. symmetric Kinetic resolution of secondary alcohols in water.
4. Enantioselective Reformatsky reaction with ketones.

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE(138124-32-0)Related Product Information

• (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
• (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
• Manganese
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• (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE
• CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE
• N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE
• N-benzylidenecyclohexylamine
• N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE
• (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
• N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE
• (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE