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9-Bromoanthracene

Basic information Description References Safety Related Supplier

9-Bromoanthracene Basic information

Product Name:
9-Bromoanthracene
CAS:
1564-64-3
MF:
C14H9Br
MW:
257.13
EINECS:
216-359-3
Mol File:
1564-64-3.mol
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9-Bromoanthracene Chemical Properties

Melting point:
97-100 °C(lit.)
Boiling point:
303.85°C (rough estimate)
Density 
1.4251 (rough estimate)
refractive index 
1.6404 (estimate)
storage temp. 
0-6°C
form 
Powder
color 
Yellow
Water Solubility 
Insoluble in water.
BRN 
1869747
InChIKey
ZIRVQSRSPDUEOJ-UHFFFAOYSA-N
CAS DataBase Reference
1564-64-3(CAS DataBase Reference)
NIST Chemistry Reference
9-Bromoanthracene(1564-64-3)
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Safety Information

Hazard Codes 
Xi
Safety Statements 
22-24/25
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29049090

MSDS

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9-Bromoanthracene Usage And Synthesis

Description

9-bromoanthracene is a kind of bromine-derived anthracene. It is known to be able to reversibly photodimerize in a head-to tail fashion upon irradiation by long-wavelength ultraviolet light. The photodimers of 9-bromoanthracene are suitable to be used as alkyl halide initiators in the atom transfer radical polymerization (ATRP) reactions. It is also used as the intermediate for the preparation of the 9-substitued form of the polycyclic aromatic hydrocarbon (PAH) anthracene.

References

Cohen, Nicole A., et al. Macromolecular Chemistry and Physics 210.3 ‐4 (2009): 263-268.
Xu, Xiaoming, Wenzhe Lu, and Richard B. Cole. Analytical chemistry 68.23 (1996): 4244-4253.
Dang, Hung, and Miguel A. Garcia-Garibay. Journal of the American Chemical Society 123.2 (2001): 355-356.

Chemical Properties

white to light yellow crystal powder

Purification Methods

Crystallise 9-bromoanthracene from MeOH or EtOH followed by sublimation in vacuo. [Masnori et al. J Am Chem Soc 108 126 1986, Beilstein 5 IV 2295.]

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Shijiazhuang Hao Teng Chemical Technology Co., Ltd. Gold
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13592012365
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Shanghai Dingshi Pharmaceutical Technology Co., Ltd. Gold
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16621254680
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16621254680@163.com
Basic information Description References Safety Related Supplier