2-Methylbutane Chemical Properties
- Melting point:
- -160 °C
- Boiling point:
- 30 °C(lit.)
- 0.62 g/mL at 25 °C(lit.)
- vapor density
- 2.6 (vs air)
- vapor pressure
- 11.17 psi ( 20 °C)
- refractive index
- Flash point:
- −51 °C
- storage temp.
- >14 (Schwarzenbach et al., 1993)
- Clear colorless
- explosive limit
- Water Solubility
- Miscible with water, hydrocarbons, oils, alcohol and ether.
- λ: 192 nm Amax: 1.00
λ: 210 nm Amax: 0.30
λ: 220 nm Amax: 0.07
λ: 240-400 nm Amax: 0.01
- Henry's Law Constant
- (atm?m3/mol): 1.24 at 25 °C (approximate - calculated from water solubility and vapor pressure)
- Exposure limits
- ACGIH TLV: TWA 600 ppm (adopted).
- Stable. Extremely flammable. Incompatible with strong oxidizing agents. Vapour-air mixtures explosive in certain proportions. Incompatible with rubber, various plastics. The vapour, being heavier than air, may roll over surfaces and collect in low points. Note low flash point.
- CAS DataBase Reference
- 78-78-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Butane, 2-methyl-(78-78-4)
- EPA Substance Registry System
- 2-Methylbutane (78-78-4)
2-Methylbutane Usage And Synthesis
colourless liquid with a characteristic smell
2-Methylbutane (isopentane), C5H12, is a flammable liquid and exhibits physical properties very similar to those of pentane. It has been detected in urban air.
Clear, colorless, watery, very flammable liquid with a pleasant odor. Evaporates quickly when spilled. An odor threshold concentration of 1.3 ppmv was reported by Nagata and Takeuchi (1990).
Solvent, manufacture of chlorinated derivatives, blowing agent for polystyrene.
ChEBI: An alkane that is butane substituted by a methyl group at position 2.
Isopentane is produced by fractional distillation of natural gas liquids and crude oil.
Watery colorless liquid with a gasoline-like odor. Floats on water. Flammable, irritating vapor is produced. Boiling point is 82°F.
Air & Water Reactions
Highly flammable. Insoluble in water.
2-Methylbutane is a fire and explosion hazard when in contact with oxidizing agents. .
Highly flammable, dangerous fire risk.
Inhalation causes irritation of respiratory tract, cough, mild depression, irregular heartbeat. Aspiration causes severe lung irritation, coughing, pulmonary edema; excitement followed by depression. Ingestion causes nausea, vomiting, swelling of abdomen, headache, depression.
Behavior in Fire: Highly volatile liquid. Vapors may explode when mixed with air.
Mddly toxic and narcotic by inhalation. See also PENTANE. Flammable liquid. A very dangerous fire and explosion hazard when exposed to heat, flame, or oxidzers. Keep away from sparks, heat, or open flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
A constituent in gasoline. Harley et al. (2000) analyzed the headspace vapors of three
grades of unleaded gasoline where ethanol was added to replace methyl tert-butyl ether. The
gasoline vapor concentrations of 2-methylbutane in the headspace were 24.1 wt % for regular
grade, 24.8 wt % for mid-grade, and 26.0 wt % for premium grade.
Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission rate of 2-methylbutane was 5.6 mg/kg of pine burned. Emission rates of 2-methylbutane were not measured during the combustion of oak and eucalyptus.
California Phase II reformulated gasoline contained 2-methylbutane at a concentration of 79.2g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 3.69 and 148 μg/km, respectively (Schauer et al., 2002).
Photolytic. When synthetic air containing gaseous nitrous acid and 2-methylbutane was exposed
to artificial sunlight (λ = 300–450 nm), acetone, acetaldehyde, methyl nitrate, peroxy-acetal
nitrate, propyl nitrate, and pentyl nitrate were formed (Cox et al., 1980).
Based upon a photooxidation rate constant of 3.90 x 10-12 cm3/molecule?sec with OH radicals in summer daylight, the atmospheric lifetime is 36 h (Altshuller, 1991). At atmospheric pressure and 300 K, Darnall et al. (1978) reported a rate constant of 3.78 x 10-12 cm3/molecule?sec for the same reaction.
Cox et al. (1980) reported a rate constant of 5.0 x 10-11 cm3/molecule?sec for the reaction of gaseous 2-methylbutane with OH radicals based on a value of 8 x 10-12 cm3/molecule?sec for the reaction of ethylene with OH radicals.
Chemical/Physical. Complete combustion in air produces carbon dioxide and water vapor.
2-Methylbutane will not hydrolyze because it does not contain a hydrolyzable functional group.
Stir isopentane for several hours in the cold with conc H2SO4 (to remove olefinic impurities), then wash it with H2O, aqueous Na2CO3 and H2O again. Dry it with MgSO4 and fractionally distil it using a Todd column packed with glass helices. Material transparent down to 180nm is obtained by distilling from sodium wire, and passing through a column of silica gel which had previously been dried in place at 350o for 12hours before use. [Potts J Phys Chem 20 809 1952, Beilstein 1 IV 320.]
- 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE
- 2-Ethylhexyl chloroformate
- Isovaleryl chloride
- 2-Ethylhexyl bromide
- 2-Ethylhexanoyl chloride
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