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Aniline Structure

Aniline

Chemical Properties

Melting point -6 °C (lit.)
Boiling point 184 °C (lit.)
Density  1.022 g/mL at 25 °C (lit.)
vapor density  3.22 (185 °C, vs air)
vapor pressure  0.7 mm Hg ( 25 °C)
refractive index  n20/D 1.586(lit.)
Flash point 76 °C
storage temp.  2-8°C
solubility  water: soluble
form  Liquid
pka 4.63(at 25℃)
color  APHA: ≤250
Specific Gravity 1.021
Odor Sweet, amine-like odor detectable at 0.6 to 10 ppm
Relative polarity 0.42
PH 8.8 (36g/l, H2O, 20℃)
PH Range 8.1
explosive limit 1.2-11%(V)
Water Solubility  36 g/L (20 ºC)
Merck  14,659
BRN  605631
Henry's Law Constant 1.91 at 25 °C (thermodynamic method-GC/UV spectrophotometry, Altschuh et al., 1999)
Dielectric constant 7.8(0℃)
Exposure limits TLV-TWA skin 2 ppm (~8 mg/m3) (ACGIH), 5 ppm (~19 mg/m3) (MSHA, OSHA, and NIOSH); IDLH 100 ppm (NIOSH).
Stability Stable. Incompatible with oxidizing agents, bases, acids, iron and iron salts, zinc, aluminium. Light sensitive. Combustible.
LogP 0.900
CAS DataBase Reference 62-53-3(CAS DataBase Reference)
IARC 2A (Vol. 27, Sup 7, 127)
NIST Chemistry Reference Aniline(62-53-3)
EPA Substance Registry System Aniline (62-53-3)

Safety Information

Hazard Codes  T,N,F
Risk Statements  23/24/25-40-41-43-48/23/24/25-50-68-48/20/21/22-39/23/24/25-11
Safety Statements  26-27-36/37/39-45-46-61-63-36/37-16
RIDADR  UN 1547 6.1/PG 2
WGK Germany  2
RTECS  BW6650000
8-9
Autoignition Temperature 615 °C
TSCA  Yes
HS Code  2921 41 00
HazardClass  6.1
PackingGroup  II
Hazardous Substances Data 62-53-3(Hazardous Substances Data)
Toxicity LD50 orally in rats: 0.44 g/kg (Jacobson)
IDLA 100 ppm

MSDS

Usage And Synthesis

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