(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)

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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Basic information

Product Name:
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
CAS:
188264-84-8
MF:
C36H52CoN2O2
MW:
603.74
Mol File:
188264-84-8.mol
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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Chemical Properties

Melting point:
>350 °C(lit.)
form 
Powder
color 
red-brown
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36/37/39-36/37
WGK Germany 
3

MSDS

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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Usage And Synthesis

Reaction

  1. Catalyst used in the kinetic resolution of racemic, terminal epoxides yielding a chiral diol and the unreacted enantiomer of the epoxide.
  2. Precursor to a Co(III) catalyst for the kinetic resolution of terminal epoxides with alcohols.
  3. Desymmetrization of meso-epoxides with carboxylic acids and fluoride.
  4. Catalyst for asymmetric cyclopropanation of styrene.
  5. Catalyst for copolymerization of CO2 and epoxides.
  6. Enantioselective intramolecular openings of oxetanes.

Chemical Properties

red to red-brown powder

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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)SupplierMore

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