Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Ethyl nonanoate(123-29-5)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Ethyl nonanoate
Synonyms
Ethyl nonylate
Ethyl pelargonate
Hexadeuterophenol
Phenol-d6
CAS
123-29-5
CAS
13127-88-3
Formula
C11H22O2
Formula
C6H6O
Molecular Weight
186.3
Molecular Weight
100.14
EINECS
204-615-7
EINECS
236-063-8
RTECS
RA6845000
RTECS Class
Primary Irritant
Merck
13,3870
Beilstein/Gmelin
1759169
Beilstein/Gmelin
NA
EC Class
toxic, corrosive

Physical and Chemical Properties

Appearance
Colorless crystals.
Appearance
Liquid
Solubility in water
84 g/L (20 C)
Solubility in water
Insoluble
Melting Point
40.8
Melting Point
-44
Boiling Point
180
Boiling Point
220
Vapor Pressure
0.12 (25 C)
Density
0.8660 g/cm3
Refractive Index
1.4220 (20 C)

First Aid Measures

Ingestion
Get medical aid. Wash mouth out with water.
Ingestion
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma. May cause cardiopulmonary system effects.
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Inhalation
Causes chemical burns to the respiratory tract. May cause effects similar to those described for ingestion. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. May cause systemic effects. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Skin
Causes skin burns. Substance is rapidly absorbed through the skin. May cause severe pain, swelling, tissue destruction, and possible shock. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid.
Eyes
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container.
Storage
Store in a tightly closed container. Corrosives area. Store protected from moisture. Store protected from light. Store in a cool, dry area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Store protected from light. Use only in a chemical fume hood. Discard contaminated shoes. Do not breathe dust.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification

Ingestion
May cause irritation of the digestive tract.
Inhalation
May cause respiratory tract irritation.
Skin
May cause skin irritation.
Eyes
May cause eye irritation.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 24/25 34
EC Risk Phrase
R 36/38
EC Safety Phrase
S 26 28.1 36/37/39 45
EC Safety Phrase
S 26 36
UN (DOT)
1671

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Personal Protection
Wear appropriate protective eyeglasses or chemical safety goggles, protective gloves and clothing to prevent exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Prolonged or repeated exposure may cause permanent eye damage. Effects may be delayed. Prolonged or repeated exposure may cause liver or kidney damage.

Fire Fighting Measures

Flash Point
85
Flash Point
93
Autoignition
595
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Do NOT get water inside containers.
Fire Fighting
Wear approved SCBA in full pressure-demand and full protective gear. Combustible Liquid. In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Upper exp. limit
9.5
Lower exp. limit
1.3
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Small spills/leaks
Avoid runoff into storm sewers and ditches which lead to waterways. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code
1
Disposal Code
9
Incompatibilities
Moisture, direct light, strong oxidizing agents, strong bases, strong acids.
Stability
Stable under normal temperatures and pressures. May discolor on exposure to light. Hygroscopic: absorbs moisture or water from the air.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, carbon dioxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
1671
Hazard Class
6.1
Packing Group
II
HS Code
2845 90 10
HS Code
2915 90 80
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