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7439-94-3

Name LUTETIUM
CAS 7439-94-3
EINECS(EC#) 231-103-0
Molecular Formula Lu
MDL Number MFCD00011098
Molecular Weight 174.97
MOL File 7439-94-3.mol

Chemical Properties

Appearance grey powder
Melting point  1663 °C (lit.)
Boiling point  3402 °C (lit.)
density  9.84 g/mL at 25 °C(lit.)
storage temp.  Flammables area
solubility  soluble in dilute acid solutions
form  powder
color  Silver-gray
Specific Gravity 9.842
Resistivity 54 μΩ-cm, 20°C
Water Solubility  Insoluble in water.
Sensitive  Air & Moisture Sensitive
Merck  13,5635
Exposure limits ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
History In 1907, Urbain described a process by which Marignac’s ytterbium (1879) could be separated into the two elements, ytterbium (neoytterbium) and lutetium. These elements were identical with “aldebaranium” and “cassiopeium,” independently discovered by von Welsbach about the same time. Charles James of the University of New Hampshire also independently prepared the very pure oxide, lutecia, at this time. The spelling of the element was changed from lutecium to lutetium in 1949. Lutetium occurs in very small amounts in nearly all minerals containing yttrium, and is present in monazite to the extent of about 0.003%, which is a commercial source. The pure metal has been isolated only in recent years and is one of the most difficult to prepare. It can be prepared by the reduction of anhydrous LuCl3 or LuF3 by an alkali or alkaline earth metal. The metal is silvery white and relatively stable in air. While new techniques, including ion-exchange reactions, have been developed to separate the various rare-earth elements, lutetium is still the most costly of all rare earths. It is priced at about $100/g (99.9%). 176Lu occurs naturally (97.41%) with 175Lu (2.59%), which is radioactive with a very long half-life of about 4 × 1010 years. Lutetium has 50 isotopes and isomers that are now recognized. Stable lutetium nuclides, which emit pure beta radiation after thermal neutron activation, can be used as catalysts in cracking, alkylation, hydrogenation, and polymerization. Virtually no other commercial uses have been found yet for lutetium. While lutetium, like other rare-earth metals, is thought to have a low toxicity rating, it should be handled with care until more information is available.
CAS DataBase Reference 7439-94-3(CAS DataBase Reference)
EPA Substance Registry System Lutetium (7439-94-3)

Safety Data

Hazard Codes  F,Xi
Risk Statements 
R11:Highly Flammable.
R36/38:Irritating to eyes and skin .
Safety Statements 
S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
RIDADR  UN 3089 4.1/PG 2
WGK Germany  3
TSCA  Yes
HazardClass  4.1
PackingGroup  III

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