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9-Bromoanthracene

Product Name:
9-Bromoanthracene
CAS No.
1564-64-3
Chemical Name:
9-Bromoanthracene
CBNumber:
CB5319891
Molecular Formula:
C14H9Br
Formula Weight:
257.13
MOL File:
1564-64-3.mol
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9-Bromoanthracene Property

Melting point:
97-100 °C(lit.)
Boiling point:
303.85°C (rough estimate)
Density 
1.4251 (rough estimate)
refractive index 
1.6404 (estimate)
storage temp. 
0-6°C
form 
Powder
color 
Yellow
Water Solubility 
Insoluble in water.
BRN 
1869747
InChIKey
ZIRVQSRSPDUEOJ-UHFFFAOYSA-N
CAS DataBase Reference
1564-64-3(CAS DataBase Reference)
NIST Chemistry Reference
9-Bromoanthracene(1564-64-3)
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Safety

Hazard Codes 
Xi
Safety Statements 
22-24/25
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29049090
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N-Bromosuccinimide Price More Price(9)

Sigma-Aldrich Gold
Product number:
B56609
Product name :
9-Bromoanthracene
Purity:
94%
Packaging:
5g
Price:
$52.6
Updated:
2019/12/02
Buy:
Buy
Sigma-Aldrich Gold
Product number:
B56609
Product name :
9-Bromoanthracene
Purity:
94%
Packaging:
25g
Price:
$186
Updated:
2019/12/02
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Buy
TCI Chemical Gold
Product number:
B0872
Product name :
9-Bromoanthracene
Purity:
>95.0%(GC)
Packaging:
5g
Price:
$22
Updated:
2019/12/02
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Buy
TCI Chemical Gold
Product number:
B0872
Product name :
9-Bromoanthracene
Purity:
>95.0%(GC)
Packaging:
25g
Price:
$79
Updated:
2019/12/02
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Buy
Alfa Aesar Gold
Product number:
L06733
Product name :
9-Bromoanthracene, 96%
Packaging:
5g
Price:
$55.5
Updated:
2019/12/02
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Buy
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9-Bromoanthracene Chemical Properties,Usage,Production

Description

9-bromoanthracene is a kind of bromine-derived anthracene. It is known to be able to reversibly photodimerize in a head-to tail fashion upon irradiation by long-wavelength ultraviolet light. The photodimers of 9-bromoanthracene are suitable to be used as alkyl halide initiators in the atom transfer radical polymerization (ATRP) reactions. It is also used as the intermediate for the preparation of the 9-substitued form of the polycyclic aromatic hydrocarbon (PAH) anthracene.

References

Cohen, Nicole A., et al. Macromolecular Chemistry and Physics 210.3 ‐4 (2009): 263-268.
Xu, Xiaoming, Wenzhe Lu, and Richard B. Cole. Analytical chemistry 68.23 (1996): 4244-4253.
Dang, Hung, and Miguel A. Garcia-Garibay. Journal of the American Chemical Society 123.2 (2001): 355-356.

Chemical Properties

white to light yellow crystal powder

Purification Methods

Crystallise 9-bromoanthracene from MeOH or EtOH followed by sublimation in vacuo. [Masnori et al. J Am Chem Soc 108 126 1986, Beilstein 5 IV 2295.]

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9-Bromoanthracene Suppliers

Global(308)Suppliers
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Germany
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1564-64-3, 9-BromoanthraceneRelated Search:

1-BROMOANTHRACENE 9,10-Dibromoanthracene-2-sulfonic Acid, Sodium Salt 7-BROMOBENZ[A]ANTHRACENE 2-TERTBUTYL-9,10-DIBROMOANTHRACENE 9,10-Dibromoanthracene 10-BROMOANTHRACENE-9-BORONIC ACID RARECHEM AQ BD AN06 10,10'-Dibromo-9,9'-bianthryl 6-bromobenzo(a)pyrene 9,10-DIBROMO-2-METHYLANTHRACENE ANTHRACENE, 9-BROMO-10-(1-NAPHTHALENYL)- 9-Bromo-10-(2-naphthyl)anthracene 1,4,9,10-TETRABROMO-ANTHRACENE 9,10-DIBROMOANTHRACENE-2-SULFONIC ACID 1,3,9,10-TETRABROMO-ANTHRACENE 9-Bromoanthracene 2,3,9,10-TETRABROMO-ANTHRACENE 9-BROMO-10-(2-METHOXY-PHENYL)-ANTHRACENE
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  • 1564-64-3
  • 1564-6-64-3
  • 15464-64-3
  • C14H9Br
  • C14H8Br
  • Anthracenes
  • Aryl
  • C13 to C37+
  • Building Blocks
  • Halogenated Hydrocarbons
  • Organic Building Blocks
  • ARYL HALIDE
  • Aromatic Compounds
  • blocks
  • Bromides
  • Aromatic Halides (substituted)
  • Anthracenes
  • Anthracene series
  • Aryl
  • C13 to C37+
  • Halogenated Hydrocarbons
  • OLED materrials
Description References