Eliminates sulfur from substituted thiophene complexes, leading to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.
It eliminates sulfur from substituted thiophene complexes, which leads to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.
This product has been enhanced for catalytic efficiency.
It usually contains 10% by weight of MeOH as stabiliser. This can be removed by keeping it in a vacuum at 0.5mm for at least 5hours. It can be sublimed slowly at high vacuum and is soluble in organic solvents. [Landesberg et al. J Org Chem 37 930 1972, Case & Whiting J Chem Soc 4632 1960, King & Stone Inorg Synth VII 193 1963.] TOXIC.
