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tert-Butyl bromoacetate

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tert-Butyl bromoacetate Basic information

Product Name:
tert-Butyl bromoacetate
CAS:
5292-43-3
MF:
C6H11BrO2
MW:
195.05
EINECS:
226-133-6
Mol File:
5292-43-3.mol
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tert-Butyl bromoacetate Chemical Properties

Melting point:
44-47 °C
Boiling point:
50 °C10 mm Hg(lit.)
Density 
1.338
refractive index 
n20/D 1.445(lit.)
Flash point:
121 °F
storage temp. 
0-6°C
form 
Liquid
color 
Clear colorless to yellow
Specific Gravity
1.333 (20/4℃)
Water Solubility 
Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Sensitive 
Lachrymatory
BRN 
1753010
InChIKey
BNWCETAHAJSBFG-UHFFFAOYSA-N
CAS DataBase Reference
5292-43-3(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
EPA Substance Registry System
Acetic acid, bromo-, 1,1-dimethylethyl ester (5292-43-3)
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Safety Information

Hazard Codes 
Xi,F
Risk Statements 
10-36/37/38
Safety Statements 
26-24/25-16
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
19
Hazard Note 
Irritant/Flammable/Lachrymatory
TSCA 
T
HazardClass 
3
PackingGroup 
III
HS Code 
29159080

MSDS

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tert-Butyl bromoacetate Usage And Synthesis

Chemical Properties

clear colorless to yellow liquid

Uses

tert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.

Purification Methods

Dissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]

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tert-Butyl bromoacetateSupplierMore

Yancheng Longshen Chemical Co.,Ltd. Gold
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0515-88718898-
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Anqing PhiChem Corporation Gold
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Nanjing Vital Chemical Co., Ltd. Gold
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Please Send Email QQ:18652950785
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chemweiao@163.com
Nanjing Vital Chemical Co., Ltd. Gold
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025-87193546-
Email:
chemweiao@163.com;
Kingfirst Chemical (Nanjing) Co.,Ltd Gold
Tel:
+86-025-84522992 84524602 13805186390
Email:
marketing@kingfirstchem.com
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