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网站主页CAS数据库列表 3878-45-3更多图谱三苯基瞵硫(3878-45-3)红外图谱(IR2)

三苯基瞵硫

产品名称 三苯基瞵硫

CAS号3878-45-3

分子式C18H15PS

分子量294.35

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  • Mass

    MS-NW-6725          
    triphenylphosphine sulfide
    C18H15PS            (Mass of molecular ion:    294)
    

       Source Temperature: 200 °C
       Sample Temperature: 130 °C
       Direct, 75 eV
    

          18.0       1.3
          27.0       4.5
          38.0       1.2
          39.0      10.2
          45.0       1.6
          50.0      11.4
          51.0      41.4
          52.0       3.5
          56.0       2.0
          57.0       7.0
          62.0       1.4
          63.0      21.6
          65.0       7.5
          68.0       1.0
          69.0       4.4
          74.0       4.0
          75.0       3.7
          76.0       3.0
          77.0      27.8
          78.0       4.2
          80.0       2.8
          81.0       6.5
          82.0       2.6
          83.0       2.9
          87.0       1.1
          89.0       2.2
          91.0       1.3
          95.0       1.0
         102.0       2.1
         107.0      25.9
         108.0      15.2
         109.0       8.3
         115.0       7.8
         116.0       1.0
         120.0       1.0
         126.0       1.8
         127.0       1.4
         128.0       2.8
         131.0       1.1
         133.0       5.5
         139.0      34.7
         140.0       4.3
         141.0       4.2
         150.0       1.0
         151.0       2.3
         152.0      17.6
         153.0       5.1
         154.0       2.6
         157.0       7.2
         158.0       1.1
         159.0       1.2
         170.0       4.8
         171.0       1.4
         181.0       3.0
         182.0       1.7
         183.0     100.0
         184.0      17.6
         185.0      61.7
         186.0       9.1
         189.0       1.2
         215.0       9.2
         216.0       1.6
         217.0      10.5
         218.0       1.6
         259.0       1.1
         261.0       6.7
         262.0      15.6
         263.0       3.2
         293.0      40.2
         294.0      72.3
         295.0      15.9
         296.0       4.9
    

400 MHz in CDCl3

90 MHz in CDCl3


  • 1H NMR 399.65 MHz
    C18 H15 P S 0.032 g : 0.5 ml CDCl3
    triphenylphosphine sulfide
    ChemicalStructure
        Assign.     Shift(ppm)
    A 7.721 B 7.503 C 7.441 J(A,P-31)=13.3HZ, J(B,P-31)=2.1HZ, J(C,P-31)=3.1HZ 90MHZ : HSP-03-787

         Hz     ppm     Int.
    

       3104.98   7.770     31
       3099.49   7.756    126
       3097.41   7.751    601
       3096.44   7.748    827
       3094.73   7.744    400
       3091.43   7.736    271
       3089.48   7.731   1000
       3087.77   7.727    822
       3086.43   7.723    183
       3084.11   7.718    620
       3083.13   7.715    818
       3081.42   7.711    403
       3078.00   7.702    265
       3075.93   7.697    993
       3074.46   7.693    800
       3015.01   7.545     31
       3013.43   7.541     36
       3009.77   7.532    111
       3008.42   7.528    200
       3006.35   7.523    206
       3005.00   7.520    152
       3003.78   7.517    165
       3001.22   7.510    544
       2999.02   7.505    616
       2996.70   7.499    214
       2995.24   7.495    321
       2993.77   7.491    542
       2991.70   7.486    511
       2990.36   7.483    267
       2987.92   7.477     77
       2982.91   7.464    208
       2980.96   7.459    762
       2979.74   7.456    462
       2977.91   7.452    774
       2976.68   7.449    385
       2974.85   7.444    583
       2973.51   7.441    957
       2971.80   7.437    742
       2970.46   7.433    964
       2968.63   7.429    317
       2968.26   7.428    301
       2966.31   7.423    453
       2964.97   7.419    383
       2963.26   7.415    428
       2962.04   7.412    249
    


  • 1H NMR 89.56 MHz
    C18 H15 P S 0.045 g : 0.5 ml CDCl3
    triphenylphosphine sulfide
    ChemicalStructure
        Assign.     Shift(ppm)
    A 7.709 B 7.52 to 7.38

         Hz     ppm     Int.
    

        703.19   7.852    377
        701.06   7.828    443
        699.63   7.812    116
        698.00   7.794    259
        697.19   7.785    240
        696.56   7.778    326
        695.75   7.769    237
        694.31   7.753    281
        693.38   7.743    591
        691.50   7.722    109
        690.13   7.706    333
        688.06   7.683    396
        686.56   7.666    118
        685.81   7.658    163
        685.13   7.650    292
        683.63   7.634    302
        683.19   7.629    308
        681.69   7.612    170
        681.06   7.605    305
        680.31   7.597    686
        678.75   7.579    144
        677.44   7.565     99
        677.13   7.561     94
        675.75   7.546    143
        674.25   7.529    214
        673.19   7.517    276
        671.25   7.495   1000
        669.13   7.472    992
        668.38   7.463    952
        667.19   7.450    555
        666.50   7.442    805
        665.94   7.436    738
        663.94   7.414    559
        662.88   7.402    306
        662.13   7.394    290
        661.06   7.382    385
        659.69   7.366    154
        658.13   7.349     60
        657.69   7.344     67
        657.00   7.336     49
        656.25   7.328    114
        655.75   7.322     58
        655.00   7.314     50
    

in CDCl3



KBr disc



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