ChemicalBook > CAS DataBase List > White phosphorus

White phosphorus

Product Name:
White phosphorus
CAS No.
12185-10-3
Chemical Name:
White phosphorus
CBNumber:
CB82131283
Molecular Formula:
P4
Formula Weight:
123.896
MOL File:
12185-10-3.mol
More
Less

White phosphorus Property

Melting point:
44.1 (0.181mm) [MER06]
Boiling point:
277℃ [CRC10]
Density 
α: 1.83; β. 1.88 [MER06]
Water Solubility 
1 part/300,000 parts H2O; 1g/400mL absolute alcohol; 1 g/200mL CHCl2; 1g/40mL benzene [MER06]
NIST Chemistry Reference
Phosphorus tetramer(12185-10-3)
EPA Substance Registry System
Phosphorus (white or yellow) (12185-10-3)
More
Less

White phosphorus Chemical Properties,Usage,Production

Chemical Properties

Phosphorus is a white to yellow, soft, waxy solid with acrid fumes in air. White/yellow phosphorus is either a yellow or colorless, volatile, crystalline solid which darkens when exposed to light and ignites in air to form white fumes and greenish light. It has a garlic-like odor. Usually shipped or stored in water.

Potential Exposure

White or yellow phosphorus is handled away from air so that exposure is usually limited. Phosphorus was at one time used for the production of matches or “lucifers” but has long since been replaced due to its chronic toxicity. It is used in the manufacture of munitions including tracer bullets, pyrotechnics, explosives, smoke bombs; and other incendiary agents; (because it spontaneously catches fire in air) and as a smoke agent (because it produces clouds of irritating white smoke). Phosphorus is used artificial fertilizers; rodenticides, phosphor bronze alloys; semiconductors, Electro-luminescent coating; and chemicals, such as phosphoric and metallic phosphides. RP is used as a choking/pulmonary agent

Shipping

UN1338 Phosphorus, amorphous, Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN1381 Phosphorus, white, dry; under water, in solution; Phosphorus, yellow, dry; yellow, under water; in solution, Hazard Class: 4.2; Labels: 4.2-Spontaneously combustible material, 6.1Poisonous materials. UN2447 Phosphorus white, molten, Hazard Class: 4.2; Labels: 4.2-Spontaneously combustible material, 6.1-Poisonous materials.

Incompatibilities

Phosphorus, a pyrophoric solid, spontaneously ignite on contact with air, producing toxic phosphorus oxide fumes. Reacts with strong bases, releasing toxic phosphine gas. Phosphorus reacts violently with oxidizers, halogens, some metals, nitrites, sulfur, and many other compounds, causing a fire and explosion hazard. White/yellow reacts with air, halogens, halides, sulfur, oxidizers, alkali hydroxides (forming gas); and metals (forming reactive phosphides). Red is a combustible solid. Friction or contact with oxidizers can cause ignition. Incompatible with many other substances. Forms gas and phosphoric acid on contact with moisture. Opened packages of red phosphorus should be stored under inert gas blanket.

Waste Disposal

Controlled incineration followed by alkaline scrubbing and particulate removal equipment.

Less

White phosphorus Suppliers

Global(23)Suppliers
BOC Sciences
Tel:
Email:
info@bocsci.com
Country:
United States
ProdList:
9983
Advantage:
65
Credit Asia Chemical Co., Ltd.
Tel:
+86 (21) 61124340
Fax:
+86 (21) 6129-4103
Email:
sales02@forever-reagent.com
Country:
China
ProdList:
9781
Advantage:
58
Shanghai Orgchem Co.,Ltd.
Tel:
+86-21-5877 1921
Fax:
+86-21-5877 1925
Email:
info@chemofchina.com
Country:
China
ProdList:
9690
Advantage:
55
JinJinLe Chemical
Tel:
10106090
Email:
jinjinlechem@163.com
Country:
China
ProdList:
10000
Advantage:
58
Shanghai Billion Chemical Chemical Co. Ltd.
Tel:
021-58771921-
Fax:
QQ: 3440059551
Email:
info@chemofchina.com;
Country:
China
ProdList:
2999
Advantage:
58
Chemwill Asia Co.,Ltd.
Tel:
86-21-51086038
Fax:
86-21-51861608
Email:
chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com
Country:
CHINA
ProdList:
23977
Advantage:
58
Hubei Jusheng Technology Co.,Ltd.
Tel:
86-18871470254
Fax:
027-59599243
Email:
linda@hubeijusheng.com
Country:
CHINA
ProdList:
28231
Advantage:
58
Hubei xin bonus chemical co. LTD
Tel:
86-13657291602
Fax:
027-59338440
Email:
linda@hubeijusheng.com
Country:
CHINA
ProdList:
23041
Advantage:
58
career henan chemical co
Tel:
0086-371-86658258
Fax:
0086-371-86658258
Email:
factory@coreychem.com
Country:
CHINA
ProdList:
29642
Advantage:
58

12185-10-3, White phosphorusRelated Search:

Sodium carbonate METHANE Adenosine Phosphorus pentasulfide Pentane Sulfur dioxide Triethylaluminum Copper sulfate pentahydrate Nitroglycerin Ammonium chlorate Potassium URANIUM Rosin HYDROXYLAMINE Phosphorus pentoxide Phosphorus Mineral oil White phosphorus
  • white phosphorus
  • [Td-(13)-delta(4)-closo]tetraphosphorus
  • Chebi:35895
  • tetraphosphorus
  • Molecular phosphorus
  • Phosphorus tetraatomic molecule
  • Phosphorus tetramer
  • Tetraatomic phosphorus
  • Tetrahedro-tetraphosphorus
  • 12185-10-3